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If the product is not listed by specific name in Schedule 1 or 3, check if it meets any of the criteria for the hazard classes in Part 2 - Classification. Products and However, the mixture could no longer be described as "Gasoline" or "Diesel" since it would no longer have a specific name in Schedule 1. Some of the classes can be further divided into divisions, e.g., Class 1, while others do not have sub-divisions, e.g., Class 3. Subscribe to Free Newsletter Where can I get my product analyzed for classification? It exists in several forms: Elemental (metallic) mercury. If you are a consultant, you may get yourself listed in CSP business directory (free) or Download the OSH Answers app for free. This requirement is outlined in Part 5 of the TDG Regulations. Once you have determined the shipping name for the dangerous good then the UN number is listed in Column 1 of Schedule 1 (see above). [1] (b) Except as provided in this subpart, the basic description specified in paragraphs (a)(1), (2), (3), and (4) of this section must be shown in sequence with no additional information interspersed. They are preferred in the following order: If you cannot find a good match in 1, you move to 2, 3 and 4 by order. A proof of classification is a document that the consignor must provide, upon request, to the federal Minister of Transport. Class 6.1 (5.1) Packing Group I. The following provisions also apply: (i) For Class 1 materials, the quantity must be the net explosive mass. In response, we have issued some transportation-related measures and guidance. For example: UN1993, FLAMMABLE LIQUID, N.O.S. Corrosives 9. However, if these two substances were mixed, the resulting mixture of these two products would still be regulated as a dangerous good. If the product's name (e.g., chemical name) is listed in Schedule 1 or 3 then the primary hazard class is in Column 3 of Schedule 1 and in Column 2 of Schedule 3 for that shipping name. Flammable Liquids 4. Mixed Loads: dangerous good whose gross mass is 1000 kg or less, and there are at least two different dangerous goods, and the dangerous goods are contained in at least two small means of containment inside a large means of containment. For hazardous mixtures or other articles, it takes more efforts and expertise to determine an accurate UN number and proper shipping name. The primary class is the class of dangerous goods that takes precedence over any other class. WebThe subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. If the product's name is listed only in Schedule 3, use the UN number from Column 3 in this schedule to look up the product in Schedule 1. The letters UN must not be included with the number when the UN number is displayed on the primary class label. Column 4 Subsidiary Risk(s) Contains the class number(s) of any subsidiary risk(s). I, II or III) assigned to the substance or article. They are substances that are identified as Marine pollutants in the IMDG Code Index or substances that satisfy the GHS classification criteria for Hazardous to Aquatic Environment Acute 1, Chronic 1, or Chronic 2. The metal is obtained by heating cinnabar in a current of air and condensing the vapour. Note: This document is a general overview of the TDG classification requirements. Transportation of Dangerous Goods (TDG) - 9 Classes, TDG "Special Case and Special Provision Exemptions. Products and It is used for dangerous goods that do not have a specific entry by name in Schedule 1. Wastes: If the product is a waste, then the shipping name is either preceded or followed by the word waste. In addition -. International Civil Aviation Organization (ICAO) Technical Instructions for the transport of dangerous goods by air, International Maritime Dangerous Goods (IMDG) Code for the transport of dangerous goods by ship, or. (iii) For domestic shipments, primary and subsidiary hazard class or division names may be entered following the numerical hazard class or division, or following the basic description. However, if the dangerous goods are explosive, the consignor must use the classification determined by the Natural Resources Canada. Wastes: The type of packages must be indicated by description of the package (for example, 12 drums). Regulations) for the transportation of dangerous goods by road. No. The requirements for the display of the dangerous goods safety marks also depend on: Labels and placards are diamond shaped (also referred to as square on point) and must be displayed as illustrated below. The subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. Meanwhile the actual assigned category is obtained from Appendix 3 in Part 2. When shipping marine pollutants by sea, the proper shipping name shall be be supplemented with the technical name of the marine pollutant. See the example below. See table 1 below for placard requirements. Example 1: UN 1993, FLAMMABLE LIQUID, N.O.S (contains methanol and acetone); Example 2: UN 2902, PESTICIDE, LIQUID, TOXIC, N.O.S. "6%X3$dl@7H,d100K@ ^/ Mercury. On the periodic table, it has the symbol "Hg" and its atomic number is 80. Column 3 Class or Division Contains the class and, in the case of class 1, the division and compatibility group. Determine the primary class, subsidiary class(es) and packing group by using section 2.8 - Precedence of Classes in Part 2, Classification. Classification is defined in Part 1 of the TDG Regulations as: classification means, for dangerous goods, as applicable, the shipping name, the primary class, the compatibility group, the subsidiary class, the UN number, the packing group, and the infectious substance category.. More than one subsidiary class is possible. Transport Canada is closely monitoring the COVID-19 situation. Marine Pollutants: This mark is required when shipments meet the excepted quantity exemption. Gross quantity of Class 1.4 (except Class 1.4S) is 1000 kg or less, Class1.1, 1.2, 1.3 or 1.5 explosives that are not subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 10 kg, Class1.1, 1.2, 1.3 or 1.5 explosives that are subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 1000 articles. For more details, consult the legislation directly. WebSubsidiary Hazard Class6.1 Packing Group III IMDG/IMO UN-No UN2809 Proper Shipping Name Mercury Hazard Class 8 Subsidiary Hazard Class6.1 Packing Group III 15. Code 3701:1-50-23 - 3701:1-50-23 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. You need to choose a UN number (usually, 4 digits) and a proper shipping name from Dangerous Goods List that can most accurately describe your dangerous goods. WebClassifying Substances That Are Included in More Than One Class or Packing Group The Primary class is shown first, with the subsidiary classes in brackets. Are safety marks required on consolidation bins? Class 4 Substances/Products include: Flammable Solids; Substances Liable to Spontaneous Combustion; Substances That on Contact with Water Emit Flammable Gases (Water-reactive Substances), Class 5 Oxidizing Substances, including Organic Peroxides, Class 9 Miscellaneous Products, Substances or Organisms. See Column 4 in Schedule 1. See Section 2.5. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#b{ogw~0B"ty'{~Oi"v?`"DqXmImPiww#R{;?j}J3]0{ ?>]|YlbE#SsBsz/E":}NCg7ON2P5N}s/w?9LO?zZ^/1BWu~N"r~!P;1FAS*:hzQHo _+3l3E6FAsmH}]fwcxoCcbb,!7cTvt{o&h: foC"uF2c;&4m;vx?=8 ga ` !%6M`Wn-@lM;#={CSaW+r:&|gB7/ndJlXqFxs1}n]N:=jd#]5$b{9NF">OL_7!y;3~*cQlCek4o6 eeGn:9P_mO}W'^q7{X,V{TFi8Qj eg/od{QVg{*Ky3n_0ht vv@9g;OkRz~w}79!^C:[7C .{;T/tUOB9x|]\;Q7W{!~uhM Inhalation Hazard words on two opposite sides of the containment for dangerous goods: as listed in Special provision 23 in Schedule 2 of the TDG Regulations, classified in Class 6.1, Toxic substances because the dangerous good meets the inhalation toxicity criteria and Class 2.3, Toxic Gases, Elevated temperature sign (if applicable), Container certification or compliance marks as required by the standard that the container is compliant with, a placard and UN number may be displayed on two opposite sides of the intermediate bulk container, or, a label for each primary and subsidiary class as well as a UN number and a shipping name may be displayed on two opposite sides of the intermediate bulk container. If the product's name (e.g., chemical name) is listed in Schedule 1 or 3, the primary hazard class is listed in Column 3 of Schedule 1 as well as in Column 2 of Schedule 3 for that shipping name. Environmentally hazardous substance, solid, n.o.s. Dangerous goods in large means of containment (greater than 450 L) that are transported at: This sign must be displayed on each side and on each end of the large means of containment (i.e., total of 4 signs) next to each primary class placard for the dangerous goods or, if there is a subsidiary class placard, next to the subsidiary class placard. Generally, if the shipment includes dangerous goods in Class 7, Radioactive Materials, then two labels are required on the small means of containment. The solution or mixture is mentioned by name in the Dangerous Goods List; The name mentioned only applies to the pure substance; The hazard class or division, subsidiary risk, packing group or physical state of the mixture or solution is different from that of the substance mentioned; The hazard characteristics and properties of the mixture require different emergency response measures; Is it a pure substance or well-defined mixture (by use) or well-defined article? However, the safety mark requirements for large means of containment with a capacity of greater than 450 L but less than or equal to 3000 L (i.e., an intermediate bulk container) are: Placards are not required for overpacks as the definition and description for an overpack does not include large means of containment. 1. Admin. Class 2.1 Dangerous Goods Also, regardless of the quantity of dangerous goods on board, the primary class placard for each of the dangerous goods in a large means of containment must be displayed on each side and on each end of the large means of containment or means of transport. How do I determine the identification number / UN Number? The required markings for overpacks include: Placards are not required for consolidation bins as the definition and description for a consolidation bin does not include large means of containment. WV Code Reg. WebThere are 9 main classes of dangerous goods. See Section 1.17.1 in the TDG Regulations. A placard is used for a large means of containment whose capacity is more than 450 L. The marks for safety for each TDG class are shown in the OSH Answers document Transportation of Dangerous Goods (TDG) - 9 Classes. Information on how to do the assignment is provided in Section 2.36 of Part 2. Consequently, the compatibility group will be already assigned by the Natural Resources Canada. <> Yes. Chemical family name (e.g., alcohol, ketone, etc. Substances (including substances and mixtures), and articles are assigned to one of the following 9 classes according to the most predominant hazards they pose in transport. Class 3 Packing Group III. Note that the, classification (primary and subsidiary hazard classes), whether or not they are shipped under a TDG exemption, Label for the primary hazard class for each dangerous good in the package, Label for the subsidiary hazard class (if any) for each dangerous good in the package, Shipping name and technical name when required in Special Provision 16 in Schedule 2 of the TDG Regulations. Figure 3: Placard requirement and placement for a single dangerous good transported in a highway tank Image from Transport Canada. in the case of infectious substances, a doctor, scientist, veterinarian, epidemiologist, genetic engineer, pathologist, nurse, coroner, or laboratory technologist or technician. The smallest planet in our solar system and nearest to the Sun, Mercury is only slightly larger than Earth's Moon. White asbestos (chrysotile, actinolite, anthophyllite, tremolite), Dangerous Goods of Class9, Packing Group III, Liquids, not listed above, Dangerous Goods of Class9, Packing GroupIII, Solids, not listed above. The packing group for a dangerous good is determined by using the laboratory test data and comparing it to the criteria in Part 2. Oxidizing 6. What types of other dangerous goods safety marks may be required? Setup. For example, if you have a product for which you determined that the shipping name will be FLAMMABLE LIQUID, N.O.S. ), 4. WebClassification of dangerous goods is broken down into nine classes according to the type of danger materials or items present, click on a class to read more details; 1. Services Main Page. If a substance is included in more than one class or packing group, its classification is determined in the following manner: entries are assigned with special provisions 274 or 318 (see column 6 in the example below). WebMercury Factsheet. Initial boiling point is greater than 35C at an absolute pressure of 101.3 kPa. Subsection 2.2(4) and Parts 9 and 10 of the TDG Regulations authorize you to use the classification from the: Many substances in Schedule 1 are assigned one or more packing groups. (iv) for dangerous goods with a primary class of Class 1, Explosives, the compatibility group letter following the primary class. If a small means of containment is placed inside another, and the outer container is not opened during loading, transport or unloading, the label is required only on the outer small means of containment. 1. If you cannot get through, please contact us by email. You may also find an expert in CSP business directory below. Flash point: Please also see the following documents in this series: The consignor is responsible for determining the classification of dangerous goods. Browse our full range of workplace health and safety products and services. Hazard class (the primary class and possible subsidiary class/es), Packing group, compatibility group, or the infectious substance category for biohazardous substances, SHIPPING NAME (in Column 2 of Schedule 1): GASOLINE; MOTOR SPIRIT; or PETROL (when selecting the shipping name you can use one of the three listed names such as gasoline), Hazard Class (in Column 3 of Schedule 1): 3, Identification Number (in Column 1 of Schedule 1): UN1203, Packing Group (in Column 4 of Schedule 1): II, UN1096 SIGNALS, SMOKE which is not allowed to be transported on a ship. Although every effort is made to ensure the accuracy, currency and completeness of the information, CCOHS does not guarantee, warrant, represent or undertake that the information provided is correct, accurate or current. For the dangerous goods other than Class 1 DG, a Conveyance Permit (For Dangerous Goods other than Class 1 Dangerous Goods) is required. View Past Newsletter, http://www.unece.org/fileadmin/DAM/trans/danger/publi/adr/adr2011/English/Part3.pdf, http://www.phmsa.dot.gov/filename/Marine_Pollutant_Guidance.pdf, Biocides and Biocidal Product Regulations, Example: UN 1133 ADHESIVES containing flammable liquids; UN 1263, PAINT, Example: UN 1987 ALCOHOLS, N.O.S. Note 3: The containers inside the package not required to bear TDG safety marks. (viii) For authorized consumer commodities, the information provided may be either the gross mass of each package or the average gross mass of the packages. 220 M - SUBPART M - REPORTS, 105 Mass. Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers The labels must be displayed on two opposite sides of the outer surface of a small means of containment. Other dangerous goods safety marks that may be required for a shipment of dangerous goods are summarized in Table 2 below. What safety marks are required on a large means of containment (capacity 450L or more)? If you have questions or need any help, please contact our sponsor. 82-4-3k - 82-4-3k - Transportation of hazardous materials; driving and parking rules, La. ), 3. Radioactive 8. Placards are not required or are optional for some dangerous goods when the gross quantity of the dangerous goods is 500 kg or less. Ark. Mercury is a highly toxic metal and can cause skin irritation, skin rashes, allergic reactions. Are there any exemptions for placards? It would be shipped as "UN 2809, MERCURY, 8(6.1)" and assigned to Packing Group II. Select country for which that subsidiary belongs to. Hazard class placards are required when the dangerous goods are: Hazard class placards are not required or are optional when only the following dangerous goods (one or more) are present in the shipment: Examples are available from the TDG Directorates FAQ on Part 4 under the question Can you explain the current placarding requirements?. (6) For transportation by aircraft, the total net mass per package, must be shown unless a gross mass is indicated in Columns (9A) or (9B) of the 172.101 table in which case the total gross mass per package must be shown; or, for Class 7 materials, the quantity of radioactive material must be shown by activity. For example: the mixture is liquid and homogeneous and the ingredients will not separate (e.g., no visible solids or two different phases such as you would observe when oil and water are mixed). Example: UN 1263, PAINT (triethylbenzene), Class 3 PG III (27 celcius degrees c.c. For an explosive that is an article, such as Cartridges, small arms, the net explosive mass may be expressed in terms of the net mass of either the article or the explosive materials contained in the article. The alphabetical order has been determined by ignoring all numerical digits and all lower case letters that precede the first capital letter in the shipping name. Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers N2977 and UN2978). will be unavailable during this time. This sign must be displayed at or next to each entry way of the large means of containment (greater than 450 L) when the containment is fumigated with a dangerous good. Browse our full range of workplace health and safety products and services. Alkalis. Use the descriptive text written in lower case letters following a shipping name (see the example for UN1337 below) to determine the shipping name that most precisely describes the dangerous goods. If two or more dangerous goods have different UN numbers but are identified by the same placard or placards, the placard is required to be displayed only once on each side and on each end of a large means of containment regardless of how many products in the large means of containment have that class (primary or subsidiary) [See Section 4.15 in the TDG Regulations]. are classified in the Class 1 hazard class. An appropriate modifier, such as contains or containing, and/or the percentage of the technical constituent may also be used. Webmercury and mercury compounds: 0.1 mg/m3 (TWA), skin - ACGIH Threshold Limit Value (TLV): inorganic and metallic mercury, as Hg: 0.025 mg/m3 (TWA) skin, A4 Not Self-heating solid, toxic, organic, n.o.s. << Which technical names shall be given in parenthesis for generic entries and N.O.S entries? 1273 0 obj <> endobj We do not provide consultancy services. Other safety marks are shown in Table 2 in this document (below). The packing group may be preceded by the letters PG (for example, PG II); and. sponsor this page to leave your contact info on this page.. Yes. In the Dangerous Goods List, many "generic" and "not otherwise specified (N.O.S.)" It can also negatively affect reproductive health. (ii) For hazardous materials in salvage packaging, an estimate of the total quantity is acceptable. Powdered metals. when all of the dangerous good safety marks can be seen through the overpack for each class of dangerous goods that is inside it, no additional labels or safety marks are required. You can download all hazard symbols for all hazard classes above by clicking the picture below. (b) for a liquefied petroleum gas that has not been odorized, the words Not Odourized or Not Odorized or Sans odorisant. Dangerous Goods of Class4.1, Packing Group II, not listed above, Magnesium or Magnesium alloys, with more than 50% magnesium, in pellets, turnings or ribbons, Naphthalene, crude or Naphthalene, refined, Titanium sponge granules or Titanium sponge powders, Dangerous Goods of Class4.1, Packing GroupIII, not listed above, Organometallic substance, solid, pyrophoric, water-reactive, Organometallic substance, liquid, pyrophoric, water-reactive, Phosphorus, white or Phosphorus, yellow, dry or Phosphorous, yellow, in solution or Phosphorous, yellow, underwater, Dangerous Goods of Class4.2, Packing Group I, not listed above, Potassium sulphide, anhydrous or Potassium sulphide, with less than 30% water of crystallization. (a) The shipping description of a hazardous material on the shipping paper must include: (1) The identification number prescribed for the material as shown in Column (4) of the 172.101 table; (2) The proper shipping name prescribed for the material in Column (2) of the 172.101 table; (3) The hazard class or division number prescribed for the material, as shown in Column (3) of the 172.101 table. Except for Class 1, Explosives; UN numbers are only required for: those dangerous goods that must have an ERAP dangerous goods that are liquid or gas in direct contact with the large means of containment. Figure 1: Label and placard (Image from Transport Canada). Mercury and its compounds. It is determined according to the specification in section 2.8 and the Precedence of Classes Table which is provided in Part 2. WebIn 2007 Mercury Marine began selling its Zeus drive system. Can I use a UN number that is not included in the Canadian TDG Regulations? Classification is defined in Part 1 of the TDG Regulations as: classification means, for dangerous goods, as applicable, the shipping name, the primary class, the 28-35-189a - 28-35-189a - Advance notification of transport of nuclear waste, Kan. Admin. When tags are used, the UN number must be displayed on the primary class label or on the tag next to the primary class label. WebEach subsidiary must be associated with at least one nexus. For goods having multiple risks which are not specifically mentioned by name in Dangerous Goods List, you have to follow the following hazard precedence rules to determine their primary hazard class and subsidiary class. The picture below shows hazard symbols for Class 4 dangerous goods. For example, both gasoline and diesel are listed by their name in Schedule 1. }qI;<>q2=4s; y5J For hazardous materials transported by sea with a flash point at or below 60 clesius degrees, the IMDG Code requires an indication of the flash point after the proper shipping name. colour used for the safety mark (e.g., orange, red, blue). EDT. Scheduled maintenance - Thursday, July 12 at 5:00 PM For example, UN3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. has three hazard classes assigned to it in Column 3 of Schedule 1. Consult Schedule 3 for the shipping name that most precisely describes the dangerous goods. size of the means of containment (e.g., small vs. large). The number of placards depends on the type of large means of containment, classification of the dangerous good, and the type safety mark that is required. Large means of containment: These words must be displayed on two opposite sides of the large means of containment in addition to any other safety marks that are required under the TDG Regulations. The Proper Shipping Name must be preceded by the word "WASTE"; Solid transported in a molten state: Shipping name is the name of the dangerous good as it appears in column 2 of Schedule 1. This communication is accomplished by the: Note that the difference between labels and placards is their size. Ohio Admin. WebMercury (Metallic) Quicksilver; Hydrargyrum; Liquid Silver 1.2. (vii) For hazardous materials in limited quantities, the total net quantity per package must be shown unless a gross mass is indicated in Column 4 of 173.27 Table 3, in which case the total gross mass per package must be shown. As Marine Pollutants Only: p;k0;!N}?s7S&7! Developed by Mercury and its joint venture company Cummins MerCruiser Diesel (CMD), the Zeus drive is a dual Generic risk (e.g., flammable, toxic, etc.). What is the purpose of dangerous goods safety marks? See Section 2.4. This mark must be displayed on one side of a means of containment. Regs. the date on which the dangerous goods were classified. These are the primary class 2.3 and two subsidiary hazard classes 5.1 and 8. Danger placard (instead of the individual hazard class placards) may be displayed when only the following dangerous goods are present in the shipment are classified in: Class 2 gases shipment in combination of two or more cylinders that have a combined capacity exceeding 450 L such that: The combination of cylinders may be placarded as one large means of containment. WebA subsidiary class placard is required to be displayed on a large means of containment for dangerous goods that requires an emergency response assistance plan (ERAP) if they 28-35-504 - 28-35-504 - Advance notification of shipment of certain types of licensed or registered material, Kan. Admin. Go to Setup > company > Subsidiaries. That legal outcome opened the door to hire a new design and construction team to finish the North Course. The following provisions also apply: (i) For empty uncleaned packaging, only the number and type of packaging must be shown; (ii) For chemical kits and first aid kits, the total net mass of hazardous materials must be shown. Only required when a marine pollutant is being transported in a means of containment on a vessel. Shipping Name and Description This column gives the shipping names for dangerous goods in alphabetical order within each primary class and within each packing group. If you use UN 3077 or UN 3082, the proper shipping name shall also be supplemented with technical names. It exists in three forms that have different properties, usage, and toxicity. (gasoline) and the laboratory provided the following test result: Using this data and comparing it to that in Section 2.19, it is determined that this dangerous good needs to be assigned to Packing Group II. Note that these types of products do not have a UN Number. Subsidiary classes are provided in brackets and are only listed in Column 3 of Schedule 1 (not Schedule 3). The subsidiary class is the other class that further identifies the hazards of the dangerous goods. Access to this website Selecting a correct proper shipping name is not easy. Other requirements may be listed in other sections, regulations, Codes, or Acts that are not listed in this table. WebSubsidiary hazard class or division number (s) corresponding to the subsidiary risk label (s) required to be applied, when assigned, shall be entered following the primary hazard class or division and shall be enclosed in parenthesis. Generally, a large means of containment must have four placards (one on each side, one on the front and one in back). Assigning a substance into a hazard class is usually done by the consignor. This placard is not mandatory, but it is permitted on a large means of containment (greater than 450 L) instead of any other placard when the containment has: - one or more dangerous goods that require different hazard class placards, - the dangerous goods are contained in two or more small means of containment, AND - the shipment consists of only the following dangerous goods classified in: NOTE: The TDG Regulations has specified circumstances when this placard is not allowed to be used. However, it would be prudent to hire a laboratory with appropriate accreditations. How many placards are required on a large means of containment? Scheduled maintenance - Thursday, July 12 at 5:00 PM or UN 3082 ENVIRONMENTALLY HAZARODUS SUBSTANCE, LIQUID, n.o.s. Example: ETHANOL SOLUTION with more than 24% ethanol, by volume (UN1170). And how does one select a placard for different loads? Specific chemical name (e.g., acetone, sulfuric acid, etc. The (UN3291). This document may be: The proof of classification must include the following information: The TDG Directorate keeps alist of laboratoriesthat provide dangerous goods analysis and classification. Ch. Example: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Admin. Column 6 Special Provisions

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